- PII
- S26584352S0869605525040063-1
- DOI
- 10.7868/S2658435225040063
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume / Issue number 4
- Pages
- 91-100
- Abstract
- The new compound NaCu(PO)(PO(OH))Cl (x ~ 0.175) is obtained by chemical transport reactions. The crystal structure at 100 K (orthorhombic, , a = 13.6341(2), b = 13.8802(2), c = 15.5183(3) Å, V = 2936.74(8) Å, Z = 8) was solved by direct methods and refined to R = 0.022. The compound NaCu(PO)(PO(OH))Cl (x ~ 0.175) is a representative of a new structure type of inorganic compounds. Lavendulan clusters of the composition [Cu(PO)Cl] in its structure are combined into layers parallel to the (001) plane. The layers unite with each other by means of an edge-mirror linkage, resulting in the formation of a dense heteropolyhedral framework with voids occupied by Na cations. The new linkage type is the first example of edge-mirror linkage of lavendulan clusters, as opposed to the vertex-mirror and translational linkage types.
- Keywords
- минералоподобные соединения лавендулан кристаллическая структура связь лавендулановых кластеров
- Date of publication
- 09.06.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 4
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