RAS Earth ScienceЗаписки Российского минералогического общества Zapiski of the Russian Mineralogical Society

  • ISSN (Print) 0869-6055
  • ISSN (Online) 2658-4352

Selenium-Rich Native Tellurium from the Ozernovskoe Gold Deposit (Kamchatka, Russia) and Isomorphism in the Te–Se System

PII
S26584352S0869605525020055-1
DOI
10.7868/S2658435225020055
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 154 / Issue number 2
Pages
88-105
Abstract
Based on the literature and original data, an attempt to characterize the isomorphism in the native tellurium — native selenium series has been made. A Se-enriched variety of native tellurium from the Ozernovskoe gold deposit (Kamchatka, Russia) is described. This very rare variety of native tellurium is widespread here. It forms nests and veinlets up to 10 cm thick and sometimes over 1 m long, clusters of needle-like to columnar crystals up to 1 cm long. Quartz, dickite, pyrite, maletoyvayamite, fahlores of the goldfieldite subgroup, fischesserite, gachingite, bohdanowiczite, and paraguanajuatite are associated with it. The Se content in the native tellurium from the Ozernovskoe deposit varies from 0.00 to 29.9 wt%; the latter value corresponds to the formula (TeSe). Using powder X-ray diffraction and scanning electron microscopy, the homogeneity of native tellurium samples from Ozernovskoe containing 12.5, 17.8 and 29.5 wt % Se, as well as its belonging to the isomorphous tellurium-selenium series were confirmed. Probably, a complete isomorphous series in the Se–Te system is realized in nature, however, based on recent literature data, it can be assumed that ordered compounds of this system can also be formed in nature. A new type of gold-bearing mineralization, with maletoyvayamite and gachingite as the main mineral forms of gold, has been discovered in the ores enriched with native tellurium at the Ozernovskoe deposit.
Keywords
самородный теллур самородный селен Озерновское месторождение изоморфизм система Se-Te минералогия эпитермальных месторождений малетойваямит гачинтит Камчатка
Date of publication
09.03.2026
Year of publication
2026
Number of purchasers
0
Views
7

References

  1. 1. лаватских С. Ф., Трубкин Н. В. Самородный теллур и никель из высокотемпературных газовых возгонов Большого трещинного Толбачинского извержения (Камчатка) // Доклады РАН. 2003. Т. 389. № 2. С. 231—234. @@ Glavatskikh S. F., Trubkin N. V. Native tellurium and nickel from high-temperature gas sublimations of the Tolbachik volcano (Kamchatka). Proc. Russian Acad. Sci. 2003. Vol. 389. N 2. P. 231—234 (in Russian).
  2. 2. Кручинкина В. И. Исследование атомного упорядочения в кристаллических и аморфных сплавах Se-Te. Дисс. … канд. ф.‑ м. н. М., 1981. 144 с. @@ Kruchinkina V. I. Investigation of atomic ordering in crystalline and amorphous Se-Te alloys. Ph. D. thesis. Moscow: Moscow State University, 1981. 144 p. (in Russian).
  3. 3. Малышев А. И., Малышева Л. К. Самородный селен в апикальных породах Гайского медноколчеданного месторождения // Литосфера. 2023. Т. 23. № 6. С. 1095—1114. @@ Malyshev A. I., Malysheva L. K. Native selenium in the apical rocks of the Gaisky copper-pyrite deposit. Lithosphere. 2023. Vol. 23. N 6. P. 1095—1114 (in Russian).
  4. 4. Мираков М. А., Файзиев А. Р., Паутов Л. А. Самородный селен в продуктах подземного пожара Фан-Ягнобского угольного месторождения (Центральный Таджикистан) // Докл. АН Республики Таджикистан. 2017. Т. 60. № 9. С. 456—460. @@ Mirakov M. A., Fayziev A. R., Pautov L. A. Native selenium in the products of an underground fire of the Fan-Yagnob coal deposit (Central Tajikistan). Proc. Republic of Tajikistan Acad. Sci. 2017. Vol. 60. N 9. P. 456—460 (in Russian).
  5. 5. Паутов Л. А., Мираков М. А., Махмадшариф С., Карпенко В. Ю., Файзиев А. Р. Находка самородного теллура в возгонах природного подземного пожара в урочище Кухи-Малик на Фан-Ягнобском угольном месторождении (Таджикистан) // Новые данные о минералах. Т. 53. № 4. 2019. С. 95—99. @@ Pautov L. A., Mirakov M. A., Mahmadsharif S., Karpenko V. Yu., Fayziev A. R. The discovery of native tellurium in the products of a natural underground fire in the Kuhi-Malik tract at the Fan-Yagnob coal deposit (Tajikistan). New Data on Minerals. 2019. Vol. 53. N 4. P. 95—99 (in Russian).
  6. 6. Синдеева Н. Д. Минералогия, типы месторождений и основные черты геохимии селена и теллура. М.: Изд-во АН СССР, 1959. 257 с. @@ Sindeeva N. D. Mineralogy, types of deposits and the main features of the geochemistry of selenium and tellurium. Moscow: USSR Acad. Sci., 1959. 257 p. (in Russian).
  7. 7. Спиридонов Э. М., Филимонов С. В., Брызгалов И. А. Твердый раствор фишессерит-науманнит в рудах вулканогенного месторождения золота Озерновское, Камчатка// Докл. АН. 2009. Т. 425. № 3. с. 391—394. @@ Spiridonov E. M., Filimonov S. V., Bryzgalov I. A. Solid solution of fischesserite-naumannite in ores of the Ozernovskoye volcanogenic gold deposit, Kamchatka. Doklady Earth Sci. 2009. Vol. 425. P. 415—418.
  8. 8. Стрельников М. В., Пеков И. В., Япаскурт В. О., Ксенофонтов Д. А., Плетнев П. А. Высокоселенистый самородный теллур из озерновского месторождения (Камчатка) / Мат. годичной сессии РМО «Минералогические исследования в интересах развития минерально-сырьевого комплекса России и создания современных технологий». Апатиты: Изд-во ФИЦ КНЦ РАН, 2024. С. 340—341. @@ Strelnikov M. V., Pekov I. V., Yapaskurt V. O., Ksenofontov D. A., Pletnev P. A. Selenium-rich native tellurium from Ozernovskoe gold deposit (Kamchatka, Russia). In: Proc. of the Annual meeting of the RMO “Mineralogical research in the interests of the development of the mineral resource complex of Russia and the creation of modern technologies”. Apatity: Kola SC RAS, 2024. p. 340—341 (in Russian).
  9. 9. Bayliss P. Crystal chemistry and crystallography of some minerals in the tetradymite group. Amer.Miner. 1991. Vol. 76. N 1-2. P. 257—265.
  10. 10. Chen S. B., Tao W. L., Zhou Y., Zeng Z. Y., Chen X. R., Geng H. Y. Novel thermoelectric performance of 2D1T-Se2Te and SeTe2 with ultralow lattice thermal conductivity but high carrier mobility. Nanotechnology. 2021. Vol. 32. N 45. P. 1—14.
  11. 11. Coolbaugh M. F., McCormack J.K., Raudsepp M., Czech E., McMillan R., Kampf A. R. Andymcdonaldite (Fe3+2Te6+O6), a new ferric iron tellurate with inverse trirutile structure from the Detroit district, Juab County, Utah. Canad. Miner. 2020. Vol. 58. N 1. P. 85—97.
  12. 12. Dana E. S., Wells H. L. On some selenium and tellurium minerals from Honduras. Amer. Journ. Sci. Ser. 3. 1890. Vol. 40. N 235. P. 78—81.
  13. 13. Debela T. T., Kang H. S. Phase polymorphism and electronic structures of TeSe2. J. Mater. Chem. C. 2018. Vol. 6. N 38. P. 10218—10225.
  14. 14. Foulon H. Über gediegen Tellur von Fačzebaja. Neues Jahr. Miner. Geol. Palaeont. 1885. Vol. 1. P. 371—372 (in German).
  15. 15. Ghosh G., Sharma R. C., Li D. T., Chang Y. The Se-Te (Selenium-Tellurium) system. J. Phase Equilibr. 1994. Vol. 15. P. 213—224.
  16. 16. Grison E. Studies on Tellurium-Selenium Alloys. J. Chem. Phys. 1951. Vol. 19. P. 1109—1113 (in German).
  17. 17. Kotkata M. F., Mahmoud E. A., El-Mously M. K. Equilibrium diagram of selenium — tellurium system. Acta Physica Hungar. 1981. Vol. 50. P. 61.
  18. 18. Kovalenker V. A., Plotinskaya O.Yu. Te and Se mineralogy of Ozernovskoe and Prasolovskoe epithermal gold deposits, Kuril — Kamchatka volcanic belt. Geochem. Miner. Petrol. 2005. Vol. 43. P. 14—19.
  19. 19. Kudaeva Sh.S., Kozlov V. V., Skilskaya E. D., Sergeeva A. V., Tolstykh N. D., Shkilev I. A. New type of gold-bearing mineralization at the Ozernovskoe Au-Te-Se epithermal deposit (Central Kamchatka, Russia). Geol. Ore Deposits. 2024. Vol. 66. N 5. P. 547—569.
  20. 20. Liu G., Wang H., Li G. L. Structures, mobilities, electronic and optical properties of two-dimensional α-phase group-VI binary compounds: α-Se2Te and α-SeTe2. Physics Lett. A. 2020. Vol. 384. N 22. Paper 126431.
  21. 21. Nakata M., Komuro K. Chemistry and occurrences of native tellurium from epithermal gold deposits in Japan. Resource geol. 2011. Vol. 61. N 3. P. 211—223.
  22. 22. Ohmasa Y., Yamamoto I., Yao M., Endo H. Structure and Electronic Properties of Te-Se Mixtures under High Pressure. J. Physical Soc. Japan. 1995. Vol. 64. N 12. P. 4766—4789.
  23. 23. Palache C. Contributions to crystallography; claudetite, minasragrite, samsonite, native selenium, indium. Amer. Miner. 1934. Vol. 19. P. 194—205.
  24. 24. Pellini G., Vio G. Contributo allo studio dell’isomorfismo fra selenio e tellurio Atti della Reale Accademia dei Lincei. Rendiconti. Classe di scienze fìsiche, matematiche e naturali. 1906. Vol. 15. N 2. P. 46—53 (in Italian).
  25. 25. Plotinskaya O. Y., Kovalenker V. A., Seltmann R., Stanley C. J. Te and Se mineralogy of the high-sulfidation Kochbulak and Kairagach epithermal gold telluride deposits (Kurama Ridge, Middle Tien Shan, Uzbekistan). Miner. Petrol. 2006. P. 87. N 3. P. 187—207.
  26. 26. Ramiere A., Huang J., Zhao D., Zeng Y.-J. Ultralow thermal conductivity and very high Seebeck coefficient in two-dimensional TeSe2 semiconductor. Inorg. Chem. 2024. Vol. 63. P. 22162—22169.
  27. 27. Reddy K. V., Bhatnagar A. K. Semiconducting сrystalline SexTel–x alloys: X-ray and density measurements. Indian J. Pure Appl. Phys. 1984. Vol. 22. P. 596—598.
  28. 28. Sharma M. Stability, tunneling characteristics and thermoelectric properties of TeSe2 allotropes. Mater. Sci. Engineering. 2022. Vol. 280. Paper 115692.
  29. 29. Shimizu M., Stanley C. J. Coupled substitutions in goldfieldite-tetrahedrite minerals from the Iriki mine, Japan. Miner. Mag. 1991. Vol. 55. N 381. P. 515—519.
  30. 30. Sidorov E. G., Borovikov A. A., Tolstykh N. D., Bukhanova D. S., Palyanova G. A., Chubarov V. M. Gold mineralization at the Maletoyvayam deposit (Koryak Highland, Russia) and physicochemical conditions of its formation. Minerals. 2020. Vol. 10. N 12. Paper 1093.
  31. 31. Tolstykh N. D., Vymazalová A., Petrova E. A., Stenin N. Y. The Gaching Au mineralization in the Maletoivayam ore field, Kamchatka, Russia. In: Materials, Mineral Resources to Discover. Proc. of the 14th Biennial SGA Meeting. Quebéc: Society for Geology Applied to Mineral Deposits. 2017. P. 195—198.
  32. 32. Tolstykh N., Vymazalová A. Tuhy M., Shapovalova M. Conditions of formation of Au–Se-Te mineralization in the Gaching ore occurrence (Maletoyvayam ore field), Kamchatka, Russia. Miner. Mag. 2018. Vol. 82. N 3. P. 647—674.
  33. 33. Tolstykh N. D., Tuhý M., Vymazalová A., Plášil J., Laufek F., Kasatkin A. V., Nestola F., Bobrova O. V. Maletoyvayamite, Au3Se4Te6, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Miner. Mag. 2020. Vol. 84. N 1. P. 117—123.
  34. 34. Tolstykh N. D., Tuhý M., Vymazalová A., Laufek F., Plášil J., Košek F. Gachingite, Au(Te1–xSex) 0.2 ≈ x ≤ 0.5, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Miner. Mag. 2022. Vol. 86. N 2. P. 205—213.
  35. 35. Tolstykh N., Shapovalova M., Podlipsky M. Au-Ag-Se-Te-S Mineralization in the Maletoyvayam high-sulfidation epithermal deposit, Kamchatka Peninsula. Minerals. 2023. Vol. 13. N 3. Paper 420.
  36. 36. Wu B., Yin J., Ding Y., Zhang P. A new two-dimensional TeSe2 semiconductor: indirect to direct band-gap transitions. Sci. China Mater. 2017. Vol. 60. N 8. P. 747—754.
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