- PII
- S26584352S0869605525010063-1
- DOI
- 10.7868/S2658435225010063
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 150 / Issue number 1
- Pages
- 118-130
- Abstract
- A rare mineral of thallium and iodine, nataliyamalikite, TlI, was found in the products of fumarole activity occurred during the 2008-2009 eruption of the Koryaksky volcano (Kamchatka, Russia). X-ray diffraction study of nataliyamalikite confirmed that it crystallizes in the orthorhombic symmetry: space group Cmcm, a = 4.5856(2) / 4.5846(2), b = 12.9318(6) / 12.9275(4), c = 5.2551(2) / 5.2534 (6) Å, V = 311.63(2) / 311.35(6) Å3 (for two studied grains). In one of the grains, in addition to nataliyamalikite and tridymite, a cubic phase with the CsCl (Pm-3m) structure type and the unit-cell parameter a = 4.215 Å was found. This phase most likely corresponds to the cubic polymorph of TlI that is isotypic to its synthetic analogue (Pm-3m, a = 4.205-4.210 Å) and lafossaite TlCl (Pm-3m, a = 3.876 Å). The presence of cubic modification in nature continues earlier by finds of TlI crystals of cubic habit at Avachinsky and Mutnovsky volcanoes (Kamchatka). The intergrowth of two polymorphs of TlI composition, one of which is orthorhombic (nataliyamalikite), and the second corresponds to an unnamed cubic natural compound, can be caused by an evolution in the crystallization temperature. In all known cases, the formation of natalyamalikite associated with volcanic gases with a high content of the deep component.
- Keywords
- наталиямаликит таллий иод вулкан фумарола извержение иодид Корякский вулкан Камчатка
- Date of publication
- 06.12.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 15
References
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