- PII
- S2658435225060075-1
- DOI
- 10.7868/S2658435225060075
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 154 / Issue number 6
- Pages
- 135-148
- Abstract
- The crystal structure of a sulfite-bearing analogue of afghanite [sp. gr. , = 12.7664(6), = 21.4544(9) Å, = 3028.2(3) Å, = 4; = 0.0773 for 3146 independent reflections with > 2σ with the crystal chemical formula ()()()()()) from the Malobystrinskoe lazurite deposit (Southwestern Baikal region, Siberia, Russia) has been studied. In the mineral groups completely fill one of the positions in the cage of the tetrahedral framework, first found in the structure of liottite and named the liottite cage. It has been shown that the presence of groups in namely and only the liottite cage is also characteristic of other multilayer minerals of the cancrinite group with this cage: alloriite and its sulfite analogue, steudelite, tounkite, and marinellite. The possible role of reducing conditions in the formation of - bearing cancrinite-group minerals and the formation of aluminosilicate frameworks containing a liottite cage is discussed.
- Keywords
- афганит группа канкринита лиоттитовая полость сульфит-ион кристаллическая структура Малобыстринское месторождение лазурита
- Date of publication
- 16.10.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 7
References
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