- PII
- S2658435225060051-1
- DOI
- 10.7868/S2658435225060051
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 154 / Issue number 6
- Pages
- 91-108
- Abstract
- The paper presents the results of complex crystallographic, mineralogical and U-Pb (ID-TIMS) geochronological studies of wiliuite from akhtarandite rocks of the Siberian trap province. The crystallochemical characteristics of the boron-bearing variety of vesuvianite group minerals (VGM) are studied and described in detail in the aim to identify specific features that allow them to be used as geochronometer minerals. The obtained U-Pb age estimate (250±1 Ma) in good agreement with the age of the Erbeyek massif formation during the process Siberian traps and indicates the fundamental possibility of using wiliuite to obtain reliable geochronological information of the age of contact-reaction processes. The stability of the U-Pb system of wiliuite during alteration processes widely manifested in this region is demonstrated. Based on the research results, the studied wiliuite sample is recommended for use as a natural single-matrix reference material for U-Pb geochronological studies of vesuvianite group minerals.
- Keywords
- везувиан вилюит ахтарандит U-Pb (ID-TIMS) Сибирские траппы
- Date of publication
- 16.10.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 8
References
- 1. Agilent Technologies CrysAlis CCD and CrysAlis RED. Oxford Diffr. Ltd, Yarnton, Oxfordsh. 2014.
- 2. Bellatreccia F., Cámara F., Ottolini L., Della Ventura G., Cibin G., Mottana A. Wiluite from Ariccia, Latium, Italy: occurrence and crystal structure. Canad. Miner. 2005. Vol. 43. P. 1457—1468.
- 3. Chukanov N. V., Panikorovskii T. L., Chervonnvi A. D. On the relationship between the crystallochemical characteristics of minerals of the vesuvian group and their IR spectra. Zapiski RMO (Proc. Russian Miner. Soc.). 2018. Vol. 147. N 1. P. 112—128 (in Russian).
- 4. Dolivo-Dobrovolsky D. D. MINAL, free software. http://www.dimadd.ru. Accessed 15 May 2016.
- 5. Galuskin E. V. Mineraly Grupy wezwuianu ze skal achtarandytowych (rzeka Wiluj, Jakucja). Katowice: Widawnictwo Uniwersytetu Slaskiego, 2005. 193 p. (in Polish).
- 6. Galuskin E. V., Galuskina I. O. Wiluite, Ca(Al, Mg, Fe, Ti)(B, Al,)SiO(O, OH), a new mineral species isostructural with vesuvianite, from the Sakha Republic, Russian Federation. (Discussion). Canad. Miner. 2000. Vol. 38. P. 763—764.
- 7. Galuskin E. V., Galuskina I. O., Dzierzanowski P. Chlorine in vesuvianites. Mineralogia Polonica. 2005. Vol. 36. P. 51—61.
- 8. Galuskin E. V., Galuskina I. O., Sitarz M., Stadnicka K. Si- deficient, OH-substituted, boron-bearing vesuvianite from the Wiluy River, Yakutia, Russia. Canad. Miner. 2003. Vol. 41. P. 833—842.
- 9. Groat L. A., Hawthorne F. C., Ercit T. S. The incorporation of boron into the vesuvianite structure. Canad. Miner. 1994. Vol. 32. P. 505—523.
- 10. Groat L. A., Hawthorne F. C., Ercit T. S., Grice J. D. (Wiluite, Ca(Al, Mg, Fe, Ti)(B, Al,)SiO(O, OH), a new mineral species isostructural with vesuvianite, from the Sakha Republic, Russian Federation. Canad. Miner. 1998. Vol. 36. P. 1301—1304.
- 11. Han Song-Yan, Chen Jun-Lin, Liao Can- Yun, Groat L. A., Li Deng-Feng, Zheng Si-Qi, Sun Xiao-Ming, Zhai Wei. Hydrotermal vesuvianite: a U-Pb dating mineral. Lithosphere. 2025. N 1. DOI: 10.2113/2025/lithosphere_2024_193
- 12. Kamo S. L., Czamanske G. K., Amelin Yu., Fedorenko V. A., Davis D. W., Trofimov V. R. Rapid eruption of Siberian flood- volcanic rocks and evidence for coincidence with the Permian- Triassic boundary and mass extinction at 251 Ma. Earth Planet. Sci. Lett. 2003. Vol. 214. P. 75—91.
- 13. Korobkov I. G., Evstratov A. A. Basic volcanic structures of diamond-bearing regions in the east of the Tunguska syncline. The Education and Science J. 2010. N 2. P. 16—20 (in Russian).
- 14. Kravchinsky V., Konstantinov K. M., Courtilloy V., Savrasov J. I., Valet J.-P., Cherniy S. D., Mishenin S. G., Parasotka B. S. Paleomagnetism of East Siberian traps and kimberlites: Two new poles and paleogeographic reconstructions at about 360 and 250 Ma. Geoph. Journal Intern. 2002. Vol. 148. N 1. P. 1—33.
- 15. Kurazhkovskaya V. S., Borovikova E. Yu., Dorokhova G. I., Kononov O. V., Stefanovich S. Yu. IR spectra of high-symmetric and low-symmetric vesuvianites. Zapiski VMO (Proc. Russian Miner. Soc.). 2003. Vol. 132. N 1. P. 109—120 (in Russian).
- 16. Ludwig K. R. Isoplot 3.70. A Geochronological Toolkit for Microsoft Excel. Berkeley Geochronology Center Spec. Publ. 2003. Vol. 4. P. 70.
- 17. Ludwig K. R. Pb Dat for MS- DOS, version 1.21 U. S. Geological Survey Open- File Report 88—542. 1991. 35 p.
- 18. Moiseev M. M., Panikorovskii T. L., Aksenov S. M., Mazur A. S., Mikhailova J. A., Yakovenchuk V. N., Bazai A. V., Ivanyuk G. Y., Agakhanov A. A., Shilovskikh V. V., Pekov I. V., Kasatkin A. V., Rusakov V. S., Yapaskurt V. O., Karpenko V. Y., Krivovichev S. V. Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. Phys. Chem. Miner. 2020. Vol. 47. Article 18. P. 1—14.
- 19. Oleynikov B. V. Geochemistry and ore genesis of platform mafic rocks. Novosibirsk: Nauka, 1979. 263 p. (in Russian).
- 20. Panikorovskii T. L., Krivovichev S. V., Galuskin E. V., Shilovskikh V. V., Mazur A. S., Bazai A. V. S. deficient, OH-substituted, boron-bearing vesuvianite from Sakha-Yakutia, Russia: a combined single-crystal, 1H MAS-NMR and IR spectroscopic study. Eur. J. Miner. 2016. Vol. 28. N 5. P. 931—941.
- 21. Panikorovskii T. L., Mazur A. S., Bazai A. V., Shilovskikh V. V., Galuskin E. V., Chukanov N. V., Rusakov V. S., Zhukov Yu. M., Avdontseva E. Yu., Aksenov S. M., Krivovichev S. V. X-ray diffraction and spectroscopic study of wiluite: implications for the vesuvianite-group nomenclature. Phys. Chem. Miner. 2017. Vol. 44. P. 577—593.
- 22. Panikorovskii T. L., Yakovenchuk V. N., Krivovichev S. V. An X-ray diffraction method for estimating the temperature of vesuvianite crystallization. Zapiski RMO (Proc. Russian Miner. Soc.). 2023. Vol. 152. N 2. P. 94—109 (in Russian, English translation: Geol. Ore Deposit. 2024. Vol. 66. P. 1022—1033).
- 23. Romer R. L. Vesuvianite — new tool for the U-Pb dating of skarn ore deposits. Miner. Petrol. 1992. Vol. 46. P. 331—341.
- 24. Spiridonov E. M., Gritsenko Yu. D. Epigenetic low-grade metamorphism and Co-Ni-Sb-As mineralization in the Norilsk ore field. Moscow: Nauchnyi mir, 2009. 218 p. (in Russian).
- 25. Stecy J. S., Kramers J. D. Approximation of terrestrial lead isotope evolution by a two-stage model. Earth Planet. Sci. Lett. 1975. Vol. 26. P. 207-221.
- 26. Steiger R. H., Jager E. Subcommission on geochronology: 865 conventions of the use of decay constants in geo- and cosmochronology. Earth Planet. Sci. Lett. 1977. Vol. 36. P. 359-362.
- 27. Stiefeva M. V., Panikorovskii T. L., Larin A. M., Salnikova E. B., Kotov A. B., Bortnikov V. V. Vesuvianite, a New U-Pb Geochronometer Mineral for Dating Ore Deposits. Doklady Earth Sci. 2024. Vol. 518. N 2. P. 1694- 1699.
- 28. Wei Qin-Di, Yang Ming, Romer Rolf L., Wang Hao, Yang Yue-Heng, Zhao Zi-Fu, Wu Shi-Tou, Xie Lie-Wen, Huang Chao, Xu Lei, Yang Jin-Hui, Wu Fu-Yuan In situ U-Pb geochronology of vesuvianite by LA-SF-ICP-MS. J. Analytical Atomic Spectr. 2022. N 37 (1). P. 69-81.
- 29. Zhang Yu, Song Shuling, Hollings Pete, Li Dengfeng, Shao Yongjun, Chen Huayong, Zhao Lianjie, Kamo Sandra, Jin Tingting, Yuan Lingling, Liu Qingquan, Chen Shaocong In-situ U-Pb geochronology of vesuvianite in skarn deposits. Chem. Geol. 2022. Vol. 612. P. 121136
- 30. Zhukov S. I., Stupnikova N. I., Pavlenko A. S. Absolute age of intrusions of the East Tuva region and the Yenisei ridge. Geochemistry. 1961. N 7. P. 547- 560 (in Russian).
